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31.
The(3+1)-dimensional Burgers equation, which describes nonlinear waves in turbulence and the interface dynamics,is considered. Two types of semi-rational solutions, namely, the lump–kink solution and the lump–two kinks solution, are constructed from the quadratic function ansatz. Some interesting features of interactions between lumps and other solitons are revealed analytically and shown graphically, such as fusion and fission processes. 相似文献
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目前,悬链线在竖向集中力和均布荷载共同作用下的构形分析和受力计算的理论仍不完善。针对这一问题,通过引入悬链线的几何约束方程、力平衡方程和超越方程,建立了竖向集中力与均布荷载共同作用下的非线性方程组。采用牛顿迭代法求解方程组,得到了悬链线的构形和受力情况。为了验证理论计算的正确性,进行了算例和试验验证。结果表明,算例的计算结果与文献结论保持一致,试验测得的构形和水平张力大小与理论计算的构形和水平张力大小吻合较好。本文的理论计算可以更加简单精确地计算出悬链线在竖向集中力和均布荷载共同作用下的构形和受力情况,为实际工程提供重要的理论指导。 相似文献
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In this article, we study the existence of nonoscillatory solutions of higher order differential and delay differential equations with forcing term. Some new sufficient conditions are given. We use the Schauder’s fixed point theorem to prove our results. 相似文献
36.
Hui Li Jiancheng Luo Prof. Tianbo Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(50):17949-17952
The dilute solutions behaviors of Pd12L24 metal–organic nanocage and its two PEGylated derivatives are explored. The basic nanocages can self‐assemble into vesicle‐like blackberry structures in polar solvents via counterion‐mediated attraction, whereas the PEGylated nanocages always stay as discrete ions under the same conditions, demonstrating that the PEGylation can improve the stability of the single nanocages. In addition, larger nanocages are found to self‐assemble in less polar solvents. 相似文献
37.
Synthesis of polymer with defined fluorescent end groups via reversible addition fragmentation transfer polymerization for characterizing the conformations of polymer chains in solutions 下载免费PDF全文
Ye Sha Qing Zhu Yuanxin Wan Linling Li Xiaoliang Wang Gi Xue Dongshan Zhou 《Journal of polymer science. Part A, Polymer chemistry》2016,54(15):2413-2420
A new type of chain transfer agent used in reversible addition fragmentation chain transfer (RAFT) polymerization named 9‐anthracenylmethyl (4‐cyano‐4‐(N‐carbazylcarbodithioate) pentanoate) (ACCP) was synthesized with a total yield over 75% by the incorporation of both fluorescent donor and acceptor chromophores. Polymerization of heterotelechelic α,ω end‐labeled dye‐functionalized polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(n‐butyl methacrylate) (PBMA) with adjustable molecular weights and narrow polydispersity could be conducted by a one‐pot procedure through RAFT polymerization with this bischromophore chain transfer agent. The polymerizations demonstrated “living” controlled characteristics. By taking advantage of the characteristic fluorescence resonance energy transfer (FRET) response between the polymer chain terminals, the variation of chain dimensions in solution from the dilute region to the semidilute region can be monitored by changes in the ratio of the fluorescence intensities of the carbazolyl group to the anthryl group, which lends itself to potential applications in characterizing chain dimensions in solutions for thermodynamic or dynamic studies. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2413–2420 相似文献
38.
Prediction of 195Pt NMR chemical shifts of dissolution products of H2[Pt(OH)6] in nitric acid solutions by DFT methods: how important are the counter‐ion effects? 下载免费PDF全文
Athanassios C. Tsipis Ioannis N. Karapetsas 《Magnetic resonance in chemistry : MRC》2016,54(8):656-664
195Pt NMR chemical shifts of octahedral Pt(IV) complexes with general formula [Pt(NO3)n(OH)6 ? n]2?, [Pt(NO3)n(OH2)6 ? n]4 ? n (n = 1–6), and [Pt(NO3)6 ? n ? m(OH)m(OH2)n]?2 + n ? m formed by dissolution of platinic acid, H2[Pt(OH)6], in aqueous nitric acid solutions are calculated employing density functional theory methods. Particularly, the gauge‐including atomic orbitals (GIAO)‐PBE0/segmented all‐electron relativistically contracted–zeroth‐order regular approximation (SARC–ZORA)(Pt) ∪ 6–31G(d,p)(E)/Polarizable Continuum Model computational protocol performs the best. Excellent second‐order polynomial plots of δcalcd(195Pt) versus δexptl(195Pt) chemical shifts and δcalcd(195Pt) versus the natural atomic charge QPt are obtained. Despite of neglecting relativistic and spin orbit effects the good agreement of the calculated δ 195Pt chemical shifts with experimental values is probably because of the fact that the contribution of relativistic and spin orbit effects to computed σiso 195Pt magnetic shielding of Pt(IV) coordination compounds is effectively cancelled in the computed δ 195Pt chemical shifts, because the relativistic corrections are expected to be similar in the complexes and the proper reference standard used. To probe the counter‐ion effects on the 195Pt NMR chemical shifts of the anionic [Pt(NO3)n(OH)6 ? n]2? and cationic [Pt(NO3)n(OH2)6 ? n]4 ? n (n = 0–3) complexes we calculated the 195Pt NMR chemical shifts of the neutral (PyH)2[Pt(NO3)n(OH)6 ? n] (n = 1–6; PyH = pyridinium cation, C5H5NH+) and [Pt(NO3)n(H2O)6 ? n](NO3)4 ? n (n = 0–3) complexes. Counter‐anion effects are very important for the accurate prediction of the 195Pt NMR chemical shifts of the cationic [Pt(NO3)n(OH2)6 ? n]4 ? n complexes, while counter‐cation effects are less important for the anionic [Pt(NO3)n(OH)6 ? n]2? complexes. The simple computational protocol is easily implemented even by synthetic chemists in platinum coordination chemistry that dispose limited software availability, or locally existing routines and knowhow. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
39.
Viscosity solutions to a parabolic inhomogeneous equation associated with infinity Laplacian 下载免费PDF全文
We obtain the existence and uniqueness results of viscosity solutions to the initial and boundary value problem for a nonlinear degenerate and singular parabolic inhomogeneous equation of the form ut- ΔN∞u = f,where ΔN∞denotes the so-called normalized infinity Laplacian given by ΔN∞u =1|Du|2 D2 uD u, Du. 相似文献
40.
The steady flow and heat transfer of a hybrid nanofluid past a permeable stretching/shrinking wedge with magnetic field and radiation effects are studied. The governing equations of the hybrid nanofluid are converted to the similarity equations by techniques of the similarity transformation. The bvp4c function that is available in MATLAB software is utilized for solving the similarity equations numerically. The numerical results are obtained for selected different values of parameters. The results discover that two solutions exist, up to a certain value of the stretching/shrinking and suction strengths. The critical value in which the solution is in existence decreases as nanoparticle volume fractions for copper and wedge angle parameter increase. It is also found that the hybrid nanofluid enhances the heat transfer rate compared with the regular nanofluid. The reduction of the heat transfer rate is observed with the increase in radiation parameter. The temporal stability analysis is performed to analyze the stability of the dual solutions, and it is revealed that only one of them is stable and physically reliable. 相似文献